Oxidation Kinetics of Carbon Deposited on Cerium‐Doped FePO<sub>4</sub> during Dehydration of Glycerol to Acrolein
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Bibliographic record
Abstract
Abstract A cerium‐doped FePO 4 catalyst dehydrates glycerol to acrolein in the gas phase but carbon accumulation reduces the reaction rate with time. Reaction rates may be maintained for longer times by co‐feeding low concentrations of oxygen together with the glycerol, but the acrolein yield drops proportionally to the oxygen concentration. The catalyst is easily regenerated by air and the reaction rate is proportional to both the oxygen concentration and quantity of carbon. The carbonaceous deposits may be due to both glycerol and acrolein: when either is fed to the catalyst, the CO 2 /CO ratio is close to 1; during the regeneration step, the CO 2 /CO ratio is near 4. A kinetic model of first order in both oxygen concentration and adsorbed sites characterizes the transient data very well.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.001 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.001 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it