Fourier transform microwave spectra of a “new” isomer of OCS-CO2
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Bibliographic record
Abstract
The rotational spectrum of a "new" isomer of OCS-CO(2) has been measured between 5 and 18 GHz using Fourier transform microwave spectroscopy. Both a- and b-type transitions of the parent dimer and the (13)CO(2)-containing isotopologue were fit and the resulting spectroscopic constants confirm that this is the planar O-interior, not-quite-as-parallel isomer that was experimentally observed for the first time in the recent infrared investigation of Dehghany et al. [J. Chem. Phys. 130, 224310 (2009)]. As in the infrared study, the microwave transitions of this isomer appear stronger than those of the previously reported lower energy isomer of OCS-CO(2) when helium is used as the backing gas for the supersonic expansion.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it