Mn, Mg, and Zn ilmenite group titanates: A reconnaissance rietveld study
Bibliographic record
Abstract
Ecandrewsite-geikielite (Zn 1/2 Mg 1/2 TiO 3 ), ecandrewsite-pyrophanite (Zn 1/2 Mn 1/2 TiO 3 ), pyrophanite-geikielite (Mg 1/2 Mn 1/2 TiO 3 ), and ecandrewsite-pyrophanite-geikielite (Zn 1/3 Mn 1/3 Mg 1/3 TiO 3 ) titanates were synthesized at 900–1000°C at ambient pressure. All of the compounds adopt R — ilmenite-type structures. These structures were refined by the Rietveld method from X-ray powder diffraction data. Unit cell parameters and unit cell volumes decrease with decreasing average radii of the A 2+ cation. All structures consist of distorted AO 6 and TiO 6 octahedra. In common with pyrophanite and ilmenite, the distortion of the AO 6 octahedra is less than that of the TiO 6 octahedra. Data are given for the volumes and distortion indexes of all coordination polyhedra.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.001 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.002 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".