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Record W2075556947 · doi:10.1002/cjce.20558

An expert model for estimation of the performance of direct dimethyl ether synthesis from synthesis gas

2011· article· en· W2075556947 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

venuePublished in a venue whose home country is Canada.
no affNo Canadian affiliation: this work is invisible to an affiliation-only frame.
No Canadian affiliation. An affiliation-only frame, the usual design, would never have seen this work. It is one of the works that make the case for inverting the frame.

Bibliographic record

VenueThe Canadian Journal of Chemical Engineering · 2011
Typearticle
Languageen
FieldChemical Engineering
TopicCatalysis and Oxidation Reactions
Canadian institutionsnot available
Fundersnot available
KeywordsDimethyl etherBackpropagationGradient descentSelectivityYield (engineering)Artificial neural networkChemistrySyngasApproximation errorConjugate gradient methodEtherMathematicsAnalytical Chemistry (journal)AlgorithmPhysicsArtificial intelligenceComputer scienceThermodynamicsChromatographyOrganic chemistryMethanolHydrogenCatalysis

Abstract

fetched live from OpenAlex

Abstract In this work, an artificial neural network (ANN) has been trained and tested for estimation of the performance of direct synthesis of dimethyl ether (DME) from synthesis gas. Yield and selectivity of DME production and also conversion of CO could be predicted when temperature and pressure of reactor and H 2 /CO molar ratio in feed have been specified. The results of ANN estimation for yield of DME, selectivity of DME and CO conversion are in very good agreement with experimental values. For this development, database was collected from our previous experiment. The accuracy and trend stability of the trained networks were tested against unseen data. Different training schemes for the back‐propagation learning algorithm, such as: Scaled Conjugate Gradient (SCG), Levenberg–Marquardt (LM), Gradient Descent with Momentum (GDM), variable learning rate Back propagation (GDA) and Resilient back Propagation (RP) methods were used. The SCG algorithm with seven neurons in the hidden layer shows the best suitable algorithm with the minimum average absolute relative error 0.05231.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.001
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.148
Threshold uncertainty score0.299

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.019
GPT teacher head0.208
Teacher spread0.189 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it