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Record W2075647867 · doi:10.1139/s04-022

Non-enzymatic degradation of chlorofluorocarbon 113 using cyanocobalamin under anaerobic conditions

2004· article· en· W2075647867 on OpenAlexaffvenue
David M. Bagley, I. G. Sutherland, Brent E. Sleep

Bibliographic record

VenueJournal of Environmental Engineering and Science · 2004
Typearticle
Languageen
FieldBiochemistry, Genetics and Molecular Biology
TopicPorphyrin Metabolism and Disorders
Canadian institutionsUniversity of Toronto
Fundersnot available
KeywordsChlorofluorocarbonChemistryCyanocobalaminAnaerobic exerciseDegradation (telecommunications)Nuclear chemistryInorganic chemistryBiochemistryVitamin B12Organic chemistryBiology

Abstract

fetched live from OpenAlex

Chlorofluorocarbon 113 (CFC113) was rapidly and completely degraded non-enzymatically in systems containing cyanocobalamin with titanium (III) citrate as the reductant. Hydrochlorofluorocarbon 123a (HCFC123a) accounted for up to 25% of the degraded CFC113. Chlorotrifluoroethene was also detected. Increasing concentrations of cyanocobalamin increased CFC113 removal rates asymptotically and also decreased the fraction of HCFC123a remaining. Key words: chlorofluorocarbon 113, cyanocobalamin, anaerobic degradation, non-enzymatic.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.143
Threshold uncertainty score0.224

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.005
GPT teacher head0.207
Teacher spread0.202 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations2
Published2004
Admission routes2
Has abstractyes

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