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Record W2075835833 · doi:10.1021/ie061576l

Pretreatment of Lodgepole Pine Killed by Mountain Pine Beetle Using the Ethanol Organosolv Process:  Fractionation and Process Optimization

2007· article· en· W2075835833 on OpenAlex
Xuejun Pan, Dan Xie, Richard W. Yu, Dexter Lam, J. N. Saddler

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueIndustrial & Engineering Chemistry Research · 2007
Typearticle
Languageen
FieldEngineering
TopicBiofuel production and bioconversion
Canadian institutionsUniversity of British Columbia
FundersNatural Resources CanadaNatural Sciences and Engineering Research Council of Canada
KeywordsOrganosolvCelluloseChemistryPinus contortaCellulaseLigninXyloseFormic acidHemicelluloseChromatographyEthanolBotanyFood scienceBiochemistryFermentationOrganic chemistryBiology

Abstract

fetched live from OpenAlex

Lodgepole pine ( Pinus contorta ) killed by mountain pine beetle ( Dendroctonus ponderosae ) (MPB-LPP) was evaluated for bioconversion to ethanol using the ethanol organosolv process. The pretreatment was optimized using an experimental matrix designed with response surface methodology. It was found that MPB-LPP was easy to pretreat and delignify, but gave low yields of substrate and carbohydrate as a result of excessive hydrolysis and subsequent decomposition of cellulose and hemicellulose during the pretreatment. The center-point conditions (170 °C, 60 min, 1.1% H 2 SO 4 and 65% ethanol) were close to the optimum for the recovery of glucose and ethanol organosolv lignin. At the center-point conditions, ∼75% of the cellulose present in the untreated wood was recovered in the substrate fraction, and approximately 79% of the lignin in the wood was recovered as ethanol organosolv lignin (EOL). The combined recovery of carbohydrate in the substrate and water-soluble fractions was ∼83% glucose, ∼46% mannose, ∼53% xylose, ∼78% galactose, and ∼55% arabinose. The lost carbohydrate was decomposed to furfural, hydroxymethylfurfural, and levulinic and formic acids. The substrate generated at center-point conditions from MPB-LPP was readily digestible. Cellulose-to-glucose conversion yields of ∼93% and ∼97% were achieved within 24 and 48 h, respectively, with 20 FPU of cellulase/g of cellulose.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.102
Threshold uncertainty score0.550

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.039
GPT teacher head0.313
Teacher spread0.274 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it