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Record W2076091550 · doi:10.1029/2007gl030607

Composition changes during disturbed conditions: Are mass spectrometers overestimating the concentrations of atomic oxygen?

2007· article· en· W2076091550 on OpenAlexaff
Andrew Russell, R. J. Sica, Jean-Marc Noël

Bibliographic record

VenueGeophysical Research Letters · 2007
Typearticle
Languageen
FieldPhysics and Astronomy
TopicIonosphere and magnetosphere dynamics
Canadian institutionsWestern UniversityUniversity of SaskatchewanRoyal Military College of Canada
Fundersnot available
KeywordsOxygenMass spectrometryMolecular oxygenChemistryAtmosphere (unit)SpectrometerAtomic oxygenAeronomyAnalytical Chemistry (journal)Atomic physicsEnvironmental chemistryChemical physicsPhysicsMeteorology

Abstract

fetched live from OpenAlex

Mass spectrometer measurements during disturbed conditions have shown that heavier gases like N2 and Ar can be substantially enhanced while lighter gases like He can suffer moderate to severe depletions. Quantifying the changes in atomic and molecular oxygen is usually much more difficult as most mass spectrometers are not able to distinguish between ambient molecular oxygen and the molecular oxygen created by atomic oxygen‐satellite surface reactions, but the paucity of molecular oxygen above 250 km normally allows one to attribute any molecular oxygen above 250 km to the recombination of atomic oxygen on a satellite surface. High resolution simulations presented in this study suggest that large amounts of molecular oxygen can be transported upwards by vertical winds during geomagnetic storms and that the neglect of this effect could mean that mass spectrometers are overestimating the concentrations of atomic oxygen. These overestimations can be quite significant; a mass spectrometer inferred atomic oxygen depletion of 50% at 280 km could mean that the atomic oxygen number densities are actually one‐seventh of their quiet‐time values while the simulated molecular oxygen concentrations are 25 times greater.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.007
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Simulation or modeling · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.012
Threshold uncertainty score0.023

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0010.007
Meta-epidemiology (narrow)0.0000.001
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0010.001
Science and technology studies0.0000.001
Scholarly communication0.0010.002
Open science0.0010.001
Research integrity0.0010.000
Insufficient payload (model declined to judge)0.0010.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.016
GPT teacher head0.295
Teacher spread0.279 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designSimulation or modeling
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations6
Published2007
Admission routes1
Has abstractyes

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