Nanostructured Polymer Films with Liquid Inclusions. 1. Structural Blocks
Bibliographic record
Abstract
We report the synthesis of core−shell latex particles with liquid cores and rigid shells for use as structural units in the fabrication of polymer nanostructured materials with liquid inclusions. Core- and shell-forming polymers were synthesized from the copolymers of poly(butyl acrylate) (PBA) and poly(methyl methacrylate) (PMMA) with different weight ratios PBA/PMMA in the latex core and shell. The morphology of the core−shell latex particles with fluid cores and rigid shells was examined as a function of the composition of the shell-forming polymer, the weight ratio core-forming polymer/shell-forming polymer in the composite particle, and the concentration of the cross-linking agent in the shell-forming polymer. The optimum conditions were found, under which free of defects monodispersed core−shell particles could be obtained. Factors leading to the collapse of the core−shell particle are discussed and evaluated.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.005 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".