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Record W2076562426 · doi:10.1021/ma021202d

Polystyrene-<i>b</i><i>lock</i>-polyisoprene Nanofiber Fractions. 2. Viscometric Study

2003· article· en· W2076562426 on OpenAlexaff
Guojun Liu, Xiaohu Yan, Scott Duncan

Bibliographic record

VenueMacromolecules · 2003
Typearticle
Languageen
FieldMaterials Science
TopicBlock Copolymer Self-Assembly
Canadian institutionsDefence Research and Development CanadaUniversity of Calgary
Fundersnot available
KeywordsIntrinsic viscosityPolystyreneMolar massNanofiberViscometerPolymer chemistryShearing (physics)CopolymerViscosityShear ratePersistence lengthMaterials sciencePolymer scienceChemistryComposite materialChemical engineeringPolymer

Abstract

fetched live from OpenAlex

The intrinsic viscosity of five well-characterized polystyrene- block -polyisoprene nanofiber fractions in THF was determined using viscometers of different shear rates. The values increased pronouncedly with decreasing shear rates, suggesting the ready alignment of the nanofibers along the shearing direction. The intrinsic viscosity data of the longer fractions were treated by the Yamakawa−Fujii−Yoshizaki (YFY) theory for wormlike chains to yield reasonable persistence length and hydrodynamic diameter. The validity of the YFY theory should allow the use of intrinsic viscosity in the future for evaluating the molar mass of block copolymer nanofibers.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.002

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0010.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.011
GPT teacher head0.250
Teacher spread0.239 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations18
Published2003
Admission routes1
Has abstractyes

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