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Record W2076634920 · doi:10.1002/aoc.330

Arsenic speciation in whelks, <i>Buccinum undatum</i>

2002· article· en· W2076634920 on OpenAlexaffabout
Vivian Lai, Anda S. Beach, Walter Cullen, Sankar Ray, Kenneth J. Reimer

Bibliographic record

VenueApplied Organometallic Chemistry · 2002
Typearticle
Languageen
FieldEnvironmental Science
TopicArsenic contamination and mitigation
Canadian institutionsRoyal Military College of CanadaFisheries and Oceans CanadaUniversity of British Columbia
Fundersnot available
KeywordsArsenobetaineChemistryArsenicGenetic algorithmEnvironmental chemistryInductively coupled plasma mass spectrometryDry weightInorganic arsenicChromatographyMass spectrometryEcologyBiology

Abstract

fetched live from OpenAlex

Abstract The arsenic species present in the foot muscle of whelks, Buccinum undatum , collected from Newfoundland, Canada, were characterized by using high‐performance liquid chromatography–inductively coupled plasma mass spectrometry. All samples contain high amounts of arsenic, mostly over 100 µg g −1 (as arsenic, dry weight basis), and one sample contained up to 1360 µg g −1 . These values are considerably higher than those reported in other gastropods. Speciation studies of representative samples revealed arsenobetaine as the major water‐soluble arsenic compound, together with trace amounts of an arsenosugar. No inorganic arsenic species were detected in the sample extracts, indicating that consumption of the whelks poses little human risk. Copyright © 2002 John Wiley &amp; Sons, Ltd.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesInsufficient payload (model declined to judge)
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.394
Threshold uncertainty score0.998

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0520.002

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.006
GPT teacher head0.159
Teacher spread0.153 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; both teacher heads agree on what is shown here.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations15
Published2002
Admission routes2
Has abstractyes

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