Electroreduction of nitrite catalyzed by a dinuclear ruthenium phthalocyanine modified graphite electrode
Bibliographic record
Abstract
The electrocatalytic reduction of nitrite on a dinuclear ruthenium phthalocyanine ( RuPc ) 2 modified electrode is studied, using cyclic voltammetry (cyclic voltammogram), rotating disc electrode (RDE) and ring-disc electrode (RRDE) techniques. The products of nitrite reduction are ammonia, nitrous oxide, and hydroxylamine. Depending on the experimental conditions, ammonia or nitrous oxide is formed as the main product. The initial step in the electroreduction of nitrite catalyzed by ( RuPc ) 2 is a one electron Ru II / Ru I process, followed by coordination of NO 2 − to the metal center. Formation of a nitrosyl complex prior to the electroreduction does not occur. A suitable mechanism is proposed by analyzing the rate equation and the Tafel slope.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.001 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".