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Record W2079256116 · doi:10.1002/marc.201000092

Seeded Growth and Solvent‐Induced Fragmentation of Fiberlike Polyferrocenylsilane–Polyisoprene Block Copolymer Micelles

2010· article· en· W2079256116 on OpenAlexaff
Jieshu Qian, Gérald Guérin, Graeme Cambridge, Ian Manners, Mitchell A. Winnik

Bibliographic record

VenueMacromolecular Rapid Communications · 2010
Typearticle
Languageen
FieldChemistry
TopicAdvanced Polymer Synthesis and Characterization
Canadian institutionsUniversity of Toronto
Fundersnot available
KeywordsCopolymerMicelleFragmentation (computing)SolventMaterials sciencePolymer chemistryPolymer scienceChemical engineeringChemistryPolymerOrganic chemistryComposite materialAqueous solutionComputer scienceEngineering

Abstract

fetched live from OpenAlex

Addition of a concentrated solution of PI(1000) -PFS(50) dissolved in THF to a solution of PI(1000) -PFS(50) seed micelles in decane led to the formation of uniform elongated fiberlike micelles with a narrow length distribution. When additional THF (>10 vol.-%) was added to the micelles, the micelle length decreased and the contour-length distribution broadened. This effect was shown to be inconsistent with a transition to an equilibrium, in which individual polymer molecules dissociated from and added to existing micelles. Rather, it appears that the polar solvent induced fragmentation of the fiberlike micelles.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.009
Threshold uncertainty score0.952

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.011
GPT teacher head0.245
Teacher spread0.234 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations18
Published2010
Admission routes1
Has abstractyes

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