Role of dopant incorporation on the magnetic properties of Ce1−xNixO2 nanoparticles: An electron paramagnetic resonance study
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Bibliographic record
Abstract
Nickel doping has been found to produce weak room-temperature ferromagnetism (FM) in CeO2. The saturation magnetization (Ms) of the chemically synthesized Ce1−xNixO2 samples showed a maximum for x=0.04, above which the magnetization decreased gradually. For Ce1−xNixO2 samples with x⩾0.04, an activation process involving slow annealing of the sample to 500°C increased the Ms by more than two orders of magnitude. However, no such activation effect was observed in samples with x<0.04. Electron paramagnetic resonance (EPR) technique has been exploited to understand (i) the gradual decrease in the FM and subsequent disappearance of FM with increase in x for x>0.04, and (ii) the dramatic increase in Ms in the activated Ce1−xNixO2 samples with x⩾0.04 and the absence of this behavior in samples with x<0.04. Detailed analysis by simulation of the EPR data on several as-prepared Ce1−xNixO2 samples with 0.01⩽x⩽0.10 at 5 and 300K indicates the presence of several paramagnetic species: (i) two magnetically inequivalent Ni2+ ions with the ionic spin S=1, (ii) one Ce3+ ion with spin S=1∕2, and (iii) three O2− defects with S=1∕2. The spectra of the samples with x<0.04 are dominated by a single Ni2+ EPR line ascribed to dopant ions in substitutional sites, whereas in samples with x⩾0.04, there is an additional EPR line attributed to Ni2+ ions occupying interstitial sites. In the activated sample with x=0.08, the EPR line due to the interstitial Ni2+ ions is completely absent, and only the line due to substitutional Ni2+ ions is present, suggesting that the enhanced FM arises from migration of Ni2+ ions from interstitial to substitutional sites.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
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Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it