<i>In situ</i> monitoring of protein adsorption on functionalized porous Si surfaces
Bibliographic record
Abstract
In situ monitoring of the photoluminescence (PL) of undecylenic acid functionalized porous silicon (PS) was carried out in bovine serum albumin (BSA) solution. Two factors dictated the PL behavior during the protein incubation process. A PL redshift was observed within a few hours of PS incubation in BSA solution followed by an overall gradual blueshift of the PL energy. Correlating this result with Fourier transform infrared (FTIR) spectroscopy performed before and after BSA incubation as well as with the PL and FTIR studies performed in parallel on planar Si, the redshift was attributed to the adsorption (or incorporation) of protein in the porous matrix while the blueshift was assigned to surface oxidation due to the erosion of Si nanocrystallites in the PS matrix. Understanding the protein incorporation in the PS matrix has important implications in utilizing the PL as an optical transduction method in a PS-based biosensor device.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.001 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.001 | 0.001 |
| Science and technology studies | 0.000 | 0.001 |
| Scholarly communication | 0.000 | 0.001 |
| Open science | 0.001 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".