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Record W2081844319 · doi:10.1002/chin.201420065

ChemInform Abstract: Reduction of Nitriles into Aldehydes Using a TMDS/V(O)(OiPr)<sub>3</sub> Reducing System.

2014· article· en· W2081844319 on OpenAlexaboutno aff
Stéphane Laval, Wissam Dayoub, Leyla Pehlivan, Estelle Métay, Dominique Delbrayelle, Gérard Mignani, Marc Lemaire

Bibliographic record

VenueChemInform · 2014
Typearticle
Languageen
FieldChemistry
TopicChemical Synthesis and Reactions
Canadian institutionsnot available
Fundersnot available
KeywordsChemistryReduction (mathematics)Combinatorial chemistryMedicinal chemistryOrganic chemistry

Abstract

fetched live from OpenAlex

ChemInformVolume 45, Issue 20 Isocyclic Compounds ChemInform Abstract: Reduction of Nitriles into Aldehydes Using a TMDS/V(O)(OiPr)3 Reducing System. Stephane Laval, Stephane Laval Lab. Catal. Synth. Org., CNRS, Univ. Claude Bernard, F-69622 Villeurbanne, Fr.Search for more papers by this authorWissam Dayoub, Wissam Dayoub Lab. Catal. Synth. Org., CNRS, Univ. Claude Bernard, F-69622 Villeurbanne, Fr.Search for more papers by this authorLeyla Pehlivan, Leyla Pehlivan Lab. Catal. Synth. Org., CNRS, Univ. Claude Bernard, F-69622 Villeurbanne, Fr.Search for more papers by this authorEstelle Metay, Estelle Metay Lab. Catal. Synth. Org., CNRS, Univ. Claude Bernard, F-69622 Villeurbanne, Fr.Search for more papers by this authorDominique Delbrayelle, Dominique Delbrayelle Lab. Catal. Synth. Org., CNRS, Univ. Claude Bernard, F-69622 Villeurbanne, Fr.Search for more papers by this authorGerard Mignani, Gerard Mignani Lab. Catal. Synth. Org., CNRS, Univ. Claude Bernard, F-69622 Villeurbanne, Fr.Search for more papers by this authorMarc Lemaire, Marc Lemaire Lab. Catal. Synth. Org., CNRS, Univ. Claude Bernard, F-69622 Villeurbanne, Fr.Search for more papers by this author Stephane Laval, Stephane Laval Lab. Catal. Synth. Org., CNRS, Univ. Claude Bernard, F-69622 Villeurbanne, Fr.Search for more papers by this authorWissam Dayoub, Wissam Dayoub Lab. Catal. Synth. Org., CNRS, Univ. Claude Bernard, F-69622 Villeurbanne, Fr.Search for more papers by this authorLeyla Pehlivan, Leyla Pehlivan Lab. Catal. Synth. Org., CNRS, Univ. Claude Bernard, F-69622 Villeurbanne, Fr.Search for more papers by this authorEstelle Metay, Estelle Metay Lab. Catal. Synth. Org., CNRS, Univ. Claude Bernard, F-69622 Villeurbanne, Fr.Search for more papers by this authorDominique Delbrayelle, Dominique Delbrayelle Lab. Catal. Synth. Org., CNRS, Univ. Claude Bernard, F-69622 Villeurbanne, Fr.Search for more papers by this authorGerard Mignani, Gerard Mignani Lab. Catal. Synth. Org., CNRS, Univ. Claude Bernard, F-69622 Villeurbanne, Fr.Search for more papers by this authorMarc Lemaire, Marc Lemaire Lab. Catal. Synth. Org., CNRS, Univ. Claude Bernard, F-69622 Villeurbanne, Fr.Search for more papers by this author First published: 28 April 2014 https://doi.org/10.1002/chin.201420065Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinkedInRedditWechat No abstract is available for this article. Volume45, Issue20May 20, 2014 RelatedInformation

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.441
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.014
GPT teacher head0.227
Teacher spread0.214 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

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Citations0
Published2014
Admission routes1
Has abstractyes

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