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Rare Earth Element Concentrations in the Natural Water Reference Materials (NRCC) NASS‐5, CASS‐4 and SLEW‐3

2007· article· en· W2082800908 on OpenAlexaff
Michael G. Lawrence, Balz S. Kamber

Bibliographic record

VenueGeostandards and Geoanalytical Research · 2007
Typearticle
Languageen
FieldEarth and Planetary Sciences
TopicGeochemistry and Elemental Analysis
Canadian institutionsLaurentian University
Fundersnot available
KeywordsSeawaterRare-earth elementYttriumTrace elementExtraction (chemistry)Phosphoric acidLanthanideChemistryGeologyEnvironmental chemistryNitric acidMineralogyRare earthGeochemistryInorganic chemistryChromatographyOceanography

Abstract

fetched live from OpenAlex

The rare earth element and yttrium concentrations of the NRCC reference materials North Atlantic Surface seawater, NASS‐5; Coastal Atlantic Surface Seawater, CASS‐4; and the estuarine water, SLEW‐3 have been precisely determined by ICP‐MS after ca. 1:8 preconcentration following a triple chelation using HDEHP (phosphoric acid 2‐ethylhexyl ester ‐mono and di ester mixture) in heptane, and back extraction in nitric acid. We propose reference values with uncertainties for all naturally occurring lanthanides and yttrium.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.002
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.008
Threshold uncertainty score0.016

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0010.002
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0010.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.037
GPT teacher head0.329
Teacher spread0.291 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations54
Published2007
Admission routes1
Has abstractyes

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