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Record W2083162701 · doi:10.1021/la026070w

Electrophoretic Motion of a Circular Cylindrical Particle in a Circular Cylindrical Microchannel

2002· article· en· W2083162701 on OpenAlexafffund
Chunzhen Ye, David Sinton, David Erickson, Dongqing Li

Bibliographic record

VenueLangmuir · 2002
Typearticle
Languageen
FieldChemistry
TopicElectrostatics and Colloid Interactions
Canadian institutionsUniversity of Toronto
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsMicrochannelRADIUSParticle (ecology)ElectrophoresisZeta potentialElectrolyteMechanicsParticle sizeChemistryMaterials scienceMolecular physicsPhysicsChromatographyNanotechnology

Abstract

fetched live from OpenAlex

This paper investigates the electrophoretic motion of a circular cylindrical particle with hemispherical ends in a circular cylindrical microchannel filled with an aqueous electrolyte solution. The influences of three parameters on the electrophoretic motion of the particle are considered: the ratio of the particle radius to the channel radius, a / b; the ratio of the axial length of the particle to its radius, L / a; and the ratio of the zeta potential of the channel to that of the particle, γ = ζ w /ζ p . It is assumed that the electrical double layers are thin, that is, κ a → ∞. In the analysis, the liquid phase is divided into the inner region, which consists of the electrical double layers, and the outer region, which consists of the remainder of the liquid. A theoretical model governing the inner region and the outer region has been constructed, and a force balance on the particle surface is used to determine the particle velocity. The finite element method is employed to solve the resulting set of equations. It is found that the particle velocity in a microchannel decreases as a / b increases or as L / a increases. The particle velocity is also found to decrease linearly as γ increases. On the basis of these results, an analysis of the electrophoretic separation of particles in a microchannel is presented. It is found that circular cylindrical particles of the same zeta potential, in small circular cylindrical microchannels filled with an aqueous electrolyte solution, can be separated by size.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.002
Threshold uncertainty score0.004

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.001
Scholarly communication0.0000.001
Open science0.0000.000
Research integrity0.0010.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.013
GPT teacher head0.227
Teacher spread0.214 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations63
Published2002
Admission routes2
Has abstractyes

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