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Record W2083620096 · doi:10.1063/1.4745194

Triplet-polaron quenching by charges on guest molecules in phosphorescent organic light emitting devices

2012· article· en· W2083620096 on OpenAlexaff
Hossein Zamani Siboni, Hany Aziz

Bibliographic record

VenueApplied Physics Letters · 2012
Typearticle
Languageen
FieldEngineering
TopicOrganic Light-Emitting Diodes Research
Canadian institutionsUniversity of Waterloo
Fundersnot available
KeywordsPolaronPhosphorescenceElectroluminescenceQuenching (fluorescence)ExcitonPhotoluminescenceOptoelectronicsMaterials scienceOrganic semiconductorPhotochemistryLuminescenceOLEDChemical physicsLight emissionPhosphorescent organic light-emitting diodeMoleculeLayer (electronics)ChemistryCondensed matter physicsNanotechnologyFluorescencePhysicsOpticsElectronOrganic chemistry

Abstract

fetched live from OpenAlex

We use delayed electroluminescence and photoluminescence measurements to study triplet-polaron-quenching (TPQ) mechanism in phosphorescent organic light emitting devices. Results show that the TPQ mechanism is mainly caused by charges within the bulk of the emission layer (EML) rather than by charges in the hole transport layer (HTL) or at the HTL/EML interface. Furthermore, charges on the guest rather than those on the host are found to be the most efficient in quenching excitons, revealing that guest polaronic species are the most detrimental to device efficiency. The results also show that direct injection of holes from the HTL into the guest material reduces device efficiency.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.006
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.007
GPT teacher head0.208
Teacher spread0.201 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations46
Published2012
Admission routes1
Has abstractyes

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