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Record W2083654254 · doi:10.1002/chem.201190242

Inside Cover: Interfacial Complexation Reactions of Sr<sup>2+</sup> with Octyl(phenyl)‐<i>N</i>,<i>N</i>‐diisobutylcarbamoylmethylphosphine Oxide for Understanding Its Extraction in Reprocessing Spent Nuclear Fuels (Chem. Eur. J. 47/2011)

2011· paratext· en· W2083654254 on OpenAlexaff
Yu Lu, Jing Zhang, Hubert H. Girault, Zhifeng Ding

Bibliographic record

VenueChemistry - A European Journal · 2011
Typeparatext
Languageen
FieldChemical Engineering
TopicIonic liquids properties and applications
Canadian institutionsWestern University
Fundersnot available
KeywordsChemistryExtraction (chemistry)Ionic liquidStoichiometryMass spectrometryOxideElectrochemistryStrontiumNuclear reprocessingNuclear chemistryInorganic chemistryAnalytical Chemistry (journal)Spent nuclear fuelPhysical chemistryOrganic chemistryChromatographyElectrode

Abstract

fetched live from OpenAlex

Stoichiometry and complexation equilibrium constants for the extraction of strontium from spent nuclear fuels at water|room-temperature ionic liquid (RTIL) interfaces are very important for medicinal use of radioisotopes and remediation of contaminated environments. In their Full Paper on page 13206 ff., Z. Ding et al. demonstrate their investigations on the working model by means of biphasic and normal electrospray ionization mass spectroscopy and electrochemistry at water|1,2-dichloroethane and water|RTIL micro-interfaces.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: none
GenreCandidate signal: Other · Consensus signal: none
Teacher disagreement score0.018
Threshold uncertainty score0.061

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.001
Open science0.0010.000
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0180.004

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.056
GPT teacher head0.260
Teacher spread0.203 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designNot applicable
Domainnot available
GenreOther

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2011
Admission routes1
Has abstractyes

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Same venueChemistry - A European JournalSame topicIonic liquids properties and applicationsFrench-language works237,207