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Record W2085401233 · doi:10.1002/anie.200502538

Colloidal CdSe Nanocrystals Passivated by a Dye‐Labeled Multidentate Polymer: Quantitative Analysis by Size‐Exclusion Chromatography

2006· article· en· W2085401233 on OpenAlexaff
Mingfeng Wang, Tieneke E. Dykstra, Xudong Lou, Mayrose R. Salvador, Gregory D. Scholes, Mitchell A. Winnik

Bibliographic record

VenueAngewandte Chemie International Edition · 2006
Typearticle
Languageen
FieldMaterials Science
TopicQuantum Dots Synthesis And Properties
Canadian institutionsUniversity of Toronto
Fundersnot available
KeywordsSize-exclusion chromatographyDenticityPolymerElutionNanocrystalChemistryColloidPyreneMethacrylateLigand (biochemistry)ChromatographyMaterials scienceNanotechnologyCopolymerOrganic chemistryCrystal structureBiochemistry

Abstract

fetched live from OpenAlex

Hold on tight: Pyrene-labeled poly(dimethylaminoethyl methacrylate) (Pyr-PDMAEMA) was synthesized as a multidentate ligand for CdSe nanocrystals (NCs, see picture). The mean number of polymers that bind to each NC can be determined by a quantitative analytical method based on size-exclusion chromatography. Spectroscopic characterization of the eluted particles shows that Pyr-PDMAEMA binds tightly to these NCs.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Insufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.089
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.001
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0030.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.008
GPT teacher head0.241
Teacher spread0.233 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations65
Published2006
Admission routes1
Has abstractyes

Explore more

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