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Record W2085798289 · doi:10.1139/v10-027

Removal of Cd(II) and Pb(II) complexes with glycolic acid from aqueous solutions on different ion exchangers

2010· article· en· W2085798289 on OpenAlexvenueno aff
Justyna Jachuła, Dorota Kołodyńska, Zbigniew Hubicki

Bibliographic record

VenueCanadian Journal of Chemistry · 2010
Typearticle
Languageen
FieldEnvironmental Science
TopicAdsorption and biosorption for pollutant removal
Canadian institutionsnot available
Fundersnot available
KeywordsChemistryGlycolic acidAqueous solutionSorptionLangmuirFreundlich equationIon exchangeAdsorptionInorganic chemistryCationic polymerizationChelationNuclear chemistryIonOrganic chemistry

Abstract

fetched live from OpenAlex

The sorption of Cd(II) and Pb(II) ions from aqueous solutions on different ion exchangers was investigated by using glycolic acid (GA) as a complexing agent. Glycolic acid is useful for organic synthesis in oxidation–reduction, esterification, and long-chain polymerization. The experiments were carried out by using the following chelating ion exchangers: Purolite S-930, Purolite S-940, Purolite S-950, Diaion CR-20, and Wofatit MC-50 and the cationic ion exchangers: Purolite C-104, Lewatit CNP-80, and Lewatit SP-112. The influence of the initial concentration of Cd(II) and Pb(II) and glycolic acid, pH of the solution, and phase contact time on the sorption percentage was determined in the batch experiments. Pseudo-first-order and pseudo-second-order kinetic models were used to describe the kinetic data, and the rate constants were evaluated. The experimental data, fitted using the Langmuir and Freundlich adsorption models, were applied to describe the equilibrium isotherms and determined the isotherm constants. The Cd(II) and Pb(II) concentrations in the raffinate were determined by the AAS method.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.004
Threshold uncertainty score0.008

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0010.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.010
GPT teacher head0.189
Teacher spread0.179 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations11
Published2010
Admission routes1
Has abstractyes

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Same venueCanadian Journal of ChemistrySame topicAdsorption and biosorption for pollutant removalFrench-language works237,207