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Record W2085940755 · doi:10.1063/1.2178800

Surface and adsorption properties of α-tricalcium phosphate

2006· article· en· W2085940755 on OpenAlexafffund
Xilin Yin, M. J. Stott

Bibliographic record

VenueThe Journal of Chemical Physics · 2006
Typearticle
Languageen
FieldEngineering
TopicBone Tissue Engineering Materials
Canadian institutionsQueen's University
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsAdsorptionBioceramicMoleculePhosphateAtom (system on chip)Ab initioChemistryCrystallographyMaterials scienceInorganic chemistryPhysical chemistryNanotechnologyOrganic chemistry

Abstract

fetched live from OpenAlex

The interaction between bone replacement bioceramic materials and the body will take place at the surface of the material. In the present ab initio study, we have investigated surfaces of biologically important alpha-tricalcium phosphate (TCP) and adsorption of biological species including a Ca atom, an H2O molecule, and a SiO2 fragment on the surfaces. The results show that all these species adsorb on the surfaces. The Ca atoms are strongly chemisorbed with newly created Ca-O bonds similar to those in alpha-TCP bulk in bond length; a water molecule is adsorbed and in some cases also dissociated on the surfaces with the dissociative adsorption, the predominant process; a SiO2 fragment initially linear, strongly interacted with two oxygens of different PO4 groups and eventually forms a tetrahedral SiO4-like species which might be a precursor of the silicate present in Si-TCP materials.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.036
Threshold uncertainty score0.201

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.012
GPT teacher head0.192
Teacher spread0.180 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations19
Published2006
Admission routes2
Has abstractyes

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