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Record W2085946537 · doi:10.1016/s0168-6496(03)00198-3

Photochemical effects on microbial activity in natural waters: the interaction of reactive oxygen species and dissolved organic matter

2003· article· en· W2085946537 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

fundA Canadian funder is recorded on the work.
no affNo Canadian affiliation: this work is invisible to an affiliation-only frame.
No Canadian affiliation. An affiliation-only frame, the usual design, would never have seen this work. It is one of the works that make the case for inverting the frame.

Bibliographic record

VenueFEMS Microbiology Ecology · 2003
Typearticle
Languageen
FieldEarth and Planetary Sciences
TopicMarine and coastal ecosystems
Canadian institutionsnot available
FundersNatural Sciences and Engineering Research Council of CanadaVetenskapsrådetSwedish Foundation for International Cooperation in Research and Higher Education
KeywordsDissolved organic carbonReactive oxygen speciesEnvironmental chemistryPhotochemistryPhotobleachingScavengerPhotodegradationScavengingHydroxyl radicalChemistryRadicalFluorescenceBiochemistryPhotocatalysisAntioxidant

Abstract

fetched live from OpenAlex

Bacterial utilization of dissolved organic matter (DOM) in surface waters is closely linked to photochemical transformations of DOM. Photochemically produced reactive oxygen species (ROS) play a central role in many photochemical reactions, but the role of ROS for the photochemical facilitation of bacterial utilization of DOM is previously not known. We exposed lake water with high DOM concentrations to simulated sunlight, with and without the addition of ROS scavengers, and quantified the effect on the production of CO2, the loss of DOM absorbance, and bacterial growth. The photodegradation of DOM through microbial-photochemical interactions was dependent on the action of ROS. The use of ROS scavengers in irradiations of the lake water revealed that photobleaching below 300 nm and the production of CO2 are highly dependent on the action of ROS. Photobleaching and CO2 production in irradiated waters decreased significantly with the addition of ROS scavengers, but post-irradiation bacterial growth in the samples containing an ROS scavenger increased significantly above those without. The decrease in ROS activity (CO2 production) likely caused an accumulation of bioavailable DOM and enhanced microbial processes. Rapid degradation of DOM through the action of ROS would be especially important in high DOM systems. The high photochemical ROS activity may counterbalance the positive effects on bacterial activity of DOM photolysis into bioavailable molecules.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.383
Threshold uncertainty score0.878

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.005
GPT teacher head0.184
Teacher spread0.179 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it