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Analysis of 5p<sup>6</sup>5d-(5p<sup>6</sup>5f+5p<sup>6</sup>6p+5p<sup>5</sup>5d<sup>2</sup>+5p<sup>5</sup>5d6s) Transitions in Tl XIII, Pb XIV, and Bi XV and Revised Wavelengths for 5p<sup>6</sup><sup>1</sup>S<sub>0</sub>-5p<sup>5</sup>5d(3/2, 5/2)<sub>1</sub>Transitions in Hg XIII, Tl XIV, Pb XV, and Bi XVI

2002· article· en· W2086699514 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenuePhysica Scripta · 2002
Typearticle
Languageen
FieldPhysics and Astronomy
TopicAtomic and Molecular Physics
Canadian institutionsSt. Francis Xavier University
FundersFusion Energy SciencesNatural Sciences and Engineering Research Council of CanadaNational Institute of Standards and TechnologyU.S. Department of Energy
KeywordsThalliumBismuthAnalytical Chemistry (journal)Spectral lineMercury (programming language)PhysicsMaterials scienceChemistryMetallurgy

Abstract

fetched live from OpenAlex

Spectra of mercury, thallium, lead, and bismuth were photographed from 70 Å to 250 Å on two grazing-inciden ce spectrographs with low-inductance vacuum sparks. About fifty-five 5p65d-(5p65f+5p66p+5p55d2+5p55d6s) transitions were identified in each of the spectra of Tl XIII, Pb XIV, and Bi XV. The 5d2D3/2,5/2 fine-structure interval was determined as 29267 cm-1 in Tl XIII, 33195 cm-1 in Pb XIV, and 37370 cm-1 in Bi XV. Hartree-Fock and parametric least-squares-fitting calculations were carried out to interpret the 5p65f+5p66p+5p5+5d2+5p55d6s configurations in these three ions. Earlier identifications of the 5p6 1S0-5p55d(3/2, 5/2)1 transitions in Hg XIII, Tl XIV, Pb XV, and Bi XVI were revised.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.005
metaresearch head score (Gemma)0.001
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Meta-epidemiology (broad), Science and technology studies, Scholarly communication, Open science, Research integrity, Insufficient payload (model declined to judge)
Consensus categoriesMeta-epidemiology (narrow), Science and technology studies, Research integrity, Insufficient payload (model declined to judge)
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Simulation or modeling · Consensus signal: Simulation or modeling
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.227
Threshold uncertainty score0.999

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0050.001
Meta-epidemiology (narrow)0.0120.013
Meta-epidemiology (broad)0.0160.009
Bibliometrics0.0080.016
Science and technology studies0.0060.006
Scholarly communication0.0040.008
Open science0.0070.003
Research integrity0.0050.010
Insufficient payload (model declined to judge)0.0020.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.017
GPT teacher head0.229
Teacher spread0.212 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it