Zwitterionic Poly(betaine-<i>N</i>-isopropylacrylamide) Microgels: Properties and Applications
Bibliographic record
Abstract
We report the synthesis of zwitterionic poly( N, N -dimethyl- N -(3-methacrylamidopropyl)- N -(3-sulfopropyl) ammonium betaine-isopropylacrylamide) (poly(NIPAm-SPP)) microgels prepared by free-radical precipitation polymerization. We investigated the influence of the amount of SPP and the effect of the variations in temperature, pH, and electrolyte concentration on the microgel dimensions. In the range of the concentrations of SPP studied in the present work, no expected antipolyelectrolyte behavior of the microgels was observed and the particles showed polyelectrolyte properties. The zwitterionic properties of the microgels were used for in situ template-based synthesis of gold, silver, and bimetallic gold−silver nanoparticles.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.001 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".