The interaction of patterned solutes in binary solvent mixtures
Bibliographic record
Abstract
Mean solute-solute forces and solute-induced solvent structure are investigated for pairs of chemically patterned (patched) solutes in binary mixtures near demixing coexistence. The isotropic and anisotropic hypernetted-chain integral equation theories as well as a superposition approximation are solved and compared. The patched solutes consist of one end that favors the majority species in the mixture while the other end favors the minority species. A wide range of patch sizes is considered. The isotropic and anisotropic theories are found to be in good agreement for most orientations, including the most attractive and most repulsive configurations. However, some differences arise for asymmetrical orientations where unlike ends of the solute particles face each other. In contrast, superposition often gives a rather poor approximation to the mean force, even though the results obtained for the solvent densities agree qualitatively with the anisotropic theory. The mean force is sensitive to small differences in the densities particularly near demixing. For patched solutes the influence of demixing-like behavior is evident both in the orientational dependence and in the range of the mean force acting between solutes.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".