MétaCan
Menu
Back to cohort
Record W2091521530 · doi:10.1021/la0015359

Mixed Monolayers Self-Assembled on Mica Surface

2001· article· en· W2091521530 on OpenAlexaff
Vladimir Kitaev, Minseok Seo, Mark E. McGovern, Yen-Jung Huang, Eugenia Kumacheva

Bibliographic record

VenueLangmuir · 2001
Typearticle
Languageen
FieldEngineering
TopicMolecular Junctions and Nanostructures
Canadian institutionsUniversity of Toronto
Fundersnot available
KeywordsMonolayerMicaChemistryContact angleAqueous solutionX-ray photoelectron spectroscopyBromideAnalytical Chemistry (journal)CrystallographyPolymer chemistryChemical engineeringMaterials scienceOrganic chemistry

Abstract

fetched live from OpenAlex

Mixed self-assembled monolayers (MMLs) were prepared by exposing mica to (i) a solution of octyltrichlorosilane and 2,2,2-trifluoroethyl 11-(trichlorosilyl)-undecanoate in toluene and (ii) an aqueous solution of decamethonium bromide and dodecyltrimethylammonium bromide. X-ray photoelectron spectroscopy, atomic force microscopy, and contact angle measurements were used to examine the composition, the thickness, the smoothness, and the stability of the self-assembled layers in different solvents. For both types of MMLs, we report the experimental conditions under which smooth mixed monolayers with a well-defined composition can be obtained. In silanization experiments, the ratio of silane species in the mixed layer was close to that in the solution, and the MMLs obtained from positively charged amphiphiles exhibited strong surface enrichment with dodecyltrimethylammonium bromide.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.587
Threshold uncertainty score0.367

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.008
GPT teacher head0.190
Teacher spread0.182 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations18
Published2001
Admission routes1
Has abstractyes

Explore more

Same venueLangmuirSame topicMolecular Junctions and NanostructuresFrench-language works237,207