Molecular Architectures for Trimetallic d/f/d Complexes: Magnetic Studies of a LnCu<sub>2</sub> Core
Bibliographic record
Abstract
Five new trinuclear Cu-Ln-Cu cluster complexes have been prepared by a one-pot reaction using H3bcn (tris- N,N',N''-(2-hydroxybenzyl)-1,4,7-triazacyclononane) and Ln = La(III), Nd(III), Gd(III), Dy(III), and Yb(III) where the d- and f-block metal ions are in close proximity desirable for magnetic studies. The [LnCu2(bcn)2]ClO4.nH2O complexes possess the same stoichiometry as the previously reported [LnNi2(bcn)2]ClO4.nH2O and [LnZn2(bcn)2]ClO4.nH2O systems. Additionally, the solid state structures of the LnCu2 complexes appear to be isostructural to the LnNi2 and LnZn2 species as determined by their nearly superimposable IR spectra. The similarities in the structures of the [LnTM2(bcn)2]ClO4.nH2O series, where TM = Zn(II), Ni(II), and Cu(II), allow for direct comparison of their magnetic exchange. An empirical approach, removing first-order anisotropic contributions determined from the analogous [LnZn2(bcn)2]ClO4.nH2O was used to study the d/f/d spin interactions in the [LnCu2(bcn)2]ClO4.nH2O complexes. A ferromagnetic exchange was determined where Ln = Gd(III), Dy(III), or Yb(III) and an antiferromagnetic exchange for Ln = Nd(III), identical to the magnetic exchange observed for the [LnNi2(bcn)2]ClO4.nH2O complexes. An exchange integral of 3.67 cm(-1) for the trimetallic [GdCu2(bcn)2]ClO4.3H2O species was determined using a modified spin Hamiltonian. The [Cu(Hbcn)] and the [Cu3(Hbcn)2](ClO4)2 building blocks of the larger coaggregated d/f/d species were also synthesized, and their structures are reported.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.001 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.001 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.001 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".