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Record W2092944771 · doi:10.5539/ijc.v2n1p194

Synthesis and Characterization of Sodium N,N'-dioctyl-ethylenediamine Diacyl Propionate

2010· article· en· W2092944771 on OpenAlexvenueno aff
Jian Xu, Xiujun Liu, Bin Wang, Zhijun Qiao

Bibliographic record

VenueInternational Journal of Chemistry · 2010
Typearticle
Languageen
FieldChemistry
TopicAnalytical Chemistry and Chromatography
Canadian institutionsnot available
Fundersnot available
KeywordsChemistrySuccinic anhydrideEthylenediamineAlkylationAcylationYield (engineering)PropionateSodium hydroxideOrganic chemistrySodiumNuclear chemistryCatalysisPolymer chemistryMedicinal chemistry

Abstract

fetched live from OpenAlex

Sodium N,N'-dioctyl-ethylenediamine diacyl propionate, an anionic gemini surfactant, was synthesized byethylenediamine with n-octyl bromide, followed by reaction with succinic anhydride, cesium hydroxide andtriethylamine as catalyst, through N-alkylation and N-acylation. Structure of the intermediate and final product wascharacterized by infrared spectrometer and nuclear magnetic resonance apparatus. The influences of material ratio andreaction time on the N-alkylation product yield were investigated. Experimental results showed that the yield of theN-alkylation product reached up to 64% under the optimum reaction conditions, the yield of the N-acylation productwas 39%.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.005
Threshold uncertainty score0.999

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.004
GPT teacher head0.217
Teacher spread0.213 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations6
Published2010
Admission routes1
Has abstractyes

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