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Record W2093042618 · doi:10.1039/c3mt00034f

Improved selectivity of ZnNa3DTPA vs. Na5DTPA to abstract Cd2+ from plasma proteins in vitro

2013· article· en· W2093042618 on OpenAlex
Elham Zeini Jahromi, Jürgen Gailer

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueMetallomics · 2013
Typearticle
Languageen
FieldEnvironmental Science
TopicHeavy Metal Exposure and Toxicity
Canadian institutionsUniversity of Calgary
Fundersnot available
KeywordsChelationIn vitroChemistryBlood proteinsSelectivityMetalBiochemistryStereochemistryCombinatorial chemistryInorganic chemistryOrganic chemistry

Abstract

fetched live from OpenAlex

Since no chelating agent has been clinically approved for the treatment of Cd(2+) intoxicated humans, we have previously investigated diethylenetriaminepentaacetic acid (Na5DTPA) to abstract this toxic metal from plasma proteins in vitro. In addition to the complete mobilization of Cd(2+), an inadvertent abstraction of Zn(2+) from metalloproteins was also observed. Therefore, we have evaluated the effect of ZnNa3DTPA on the plasma distribution of Ca, Cd, Cu, Fe and Zn after its addition to Cd(2+)-spiked rabbit plasma. ZnNa3DTPA was as efficient as Na5DTPA in abstracting Cd(2+) (100% removal), but it did not abstract Zn(2+). Thus, complexes between essential metals (e.g. Zn(2+)) and known chelating agents emerge as feasible candidates to decrease potential adverse side effects in patients.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.210
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.010
GPT teacher head0.212
Teacher spread0.203 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it