Stimuli-Responsive Aqueous Micelles from an ABC Metallo-Supramolecular Triblock Copolymer
Why this work is in the frame
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Bibliographic record
Abstract
A metallo-supramolecular ABC triblock copolymer containing a bis(2,2‘:6‘,2‘ ‘-terpyridine)ruthenium(II) complex as a supramolecular connection between the constituting poly(styrene)- block -poly(2-vinylpyridine) diblock and poly(ethylene oxide) block (PS 32 - b -P2VP 13 -[Ru]-PEO 70 ) has been prepared. This copolymer was further utilized in order to prepare aqueous micelles consisting of a PS core, a pH-sensitive P2VP shell, and a PEO corona. The accordingly formed micelles have been characterized by a combination of dynamic light scattering, transmission electron microscopy, and atomic force microscopy. Spherical micelles and a minor fraction of bigger aggregates were observed by these three independent techniques. The pH sensitivity of the P2VP shell could be demonstrated and the reversibility of the metallo-supramolecular complex investigated utilizing a strong competitive ligand.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.009 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it