Stimuli-Responsive Aqueous Micelles from an ABC Metallo-Supramolecular Triblock Copolymer
Bibliographic record
Abstract
A metallo-supramolecular ABC triblock copolymer containing a bis(2,2‘:6‘,2‘ ‘-terpyridine)ruthenium(II) complex as a supramolecular connection between the constituting poly(styrene)- block -poly(2-vinylpyridine) diblock and poly(ethylene oxide) block (PS 32 - b -P2VP 13 -[Ru]-PEO 70 ) has been prepared. This copolymer was further utilized in order to prepare aqueous micelles consisting of a PS core, a pH-sensitive P2VP shell, and a PEO corona. The accordingly formed micelles have been characterized by a combination of dynamic light scattering, transmission electron microscopy, and atomic force microscopy. Spherical micelles and a minor fraction of bigger aggregates were observed by these three independent techniques. The pH sensitivity of the P2VP shell could be demonstrated and the reversibility of the metallo-supramolecular complex investigated utilizing a strong competitive ligand.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".