An isotopic labeling method for determining production of volatile organohalogens by marine microalgae
Bibliographic record
Abstract
An isotopic method has been developed to establish the biological production of volatile organohalogens. The marine microalgae Porphyridium purpureum and Dunaliella tertiolecta were grown in seawater medium containing NaH13CO3, and volatile organohalogens were extracted and analyzed by gas chromatography‐mass spectrometry (GC‐MS). Isotopically labeled methyl halides were formed in each microalgal culture, and the 13CHCl3 found in the P. purpureum culture confirmed the production of chloroform reported by Scarratt and Moore (Limnol. Oceanogr. 1999. 44: 703–707). No incorporation of 13C into dichloromethane was observed, even though slightly increased CH2Cl2 concentrations were detected in both algal cultures at the end of the incubation period.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.001 |
| Meta-epidemiology (narrow) | 0.001 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.001 | 0.000 |
| Science and technology studies | 0.001 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.001 | 0.000 |
| Research integrity | 0.001 | 0.001 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".