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Record W2094275153 · doi:10.1039/c2nj40355b

Design of super-hydrophobic microporous polytetrafluoroethylene membranes

2012· article· en· W2094275153 on OpenAlex
Qinglin Huang, Changfa Xiao, Xianshe Feng, Xiaoyu Hu

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueNew Journal of Chemistry · 2012
Typearticle
Languageen
FieldEnvironmental Science
TopicMembrane Separation Technologies
Canadian institutionsUniversity of Waterloo
FundersNational Natural Science Foundation of China
KeywordsMembranePolytetrafluoroethyleneMembrane distillationChemistryMicroporous materialChemical engineeringCrystallizationContact angleMembrane structurePolymer chemistryPhase (matter)Amorphous solidDesalinationOrganic chemistry

Abstract

fetched live from OpenAlex

Polytetrafluoroethylene (PTFE) membranes with unique structures were fabricated from a mixture of a PTFE emulsion and a poly(vinyl alcohol) (PVA) aqueous solution. The formation of the micro–nano structures in the PTFE membrane was ascribed to PTFE crystallization. By controlling the cooling rate during membrane formation, various PTFE membranes with different structures and properties prepared, which showed a super-hydrophobicity with a water static contact angle (155°) and a sliding angle (8.3°) owing to their micro–nano structures. The results of DSC thermal analysis, XRD and polarized light microscope examination revealed that the micro–nano structures in the membrane were derived from improved PTFE crystallization during the cold-stretching process, resulting in a crystalline phase comprising of the micro aggregates and an amorphous phase comprising of the nano structures. The resulting membrane was shown to be highly porous while still maintaining a super-hydrophobicity. A critical transmembrane pressure of as high as 0.65 MPa was achieved because of the super-hydrophobicity of the membrane. The membranes were further investigated for use in vacuum membrane distillation (VMD), and the effects of membrane structures on the water vapour flux were studied. The VMD flux increased obviously with the increase in membrane pore size when the membrane suffered stretching.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.006
Threshold uncertainty score0.997

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0040.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.016
GPT teacher head0.235
Teacher spread0.218 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it