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Record W2094440676 · doi:10.1002/qua.20252

Attosecond localization of electrons in molecules

2004· article· en· W2094440676 on OpenAlexaff
André D. Bandrauk, S. Chelkowski, Hong Shon Nguyen

Bibliographic record

VenueInternational Journal of Quantum Chemistry · 2004
Typearticle
Languageen
FieldPhysics and Astronomy
TopicLaser-Matter Interactions and Applications
Canadian institutionsUniversité de Sherbrooke
Fundersnot available
KeywordsAttosecondPhysicsElectronHigh harmonic generationAtomic physicsUltrashort pulseAsymmetryLaserPulse (music)PhotonNonlinear systemQuantum mechanicsVoltage

Abstract

fetched live from OpenAlex

Abstract Numerical solutions of the time‐dependent Schrödinger equation for a 1D model non‐Born–Oppenheimer H are used to illustrate the nonlinear nonperturbative response of molecules to intense ( I ≥ 10 13 W/cm 2 ), ultrashort ( t < 10 fs) laser pulses. Molecular high‐order harmonic generation (MHOHG) is shown to be an example of such response and the resulting nonlinear photon emission spectrum is shown to lead to the synthesis of single attosecond (10 −18 s) pulses. Application of such ultrashort pulses to the H system results in localized electron wavepackets whose motion can be detected by asymmetry in the photoelectron spectrum generated by a subsequent probe attosecond pulse, thus leading to measurement of electron motion in molecules on the attosecond time scale. © 2004 Wiley Periodicals, Inc. Int J Quantum Chem, 2004

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.002
Threshold uncertainty score0.007

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0020.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.006
GPT teacher head0.272
Teacher spread0.265 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations145
Published2004
Admission routes1
Has abstractyes

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