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RP-HPLC Method for Determination of Metaxalone Using Box- Behnken Experimental Design.

2015· article· en· W2095098014 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

venuePublished in a venue whose home country is Canada.
no affNo Canadian affiliation: this work is invisible to an affiliation-only frame.
No Canadian affiliation. An affiliation-only frame, the usual design, would never have seen this work. It is one of the works that make the case for inverting the frame.

Bibliographic record

VenueJournal of Applied Biopharmaceutics and Pharmacokinetics · 2015
Typearticle
Languageen
FieldChemistry
TopicAnalytical Methods in Pharmaceuticals
Canadian institutionsnot available
Fundersnot available
KeywordsBox–Behnken designChromatographyResponse surface methodologyHigh-performance liquid chromatographyPhosphate buffered salineVolumetric flow rateDesign of experimentsRetention timeAcetonitrileStatistical analysisLinearityMaterials scienceChemistryAnalytical Chemistry (journal)MathematicsStatisticsEngineering

Abstract

fetched live from OpenAlex

The present study demonstrates a chemometric approach to identify the significant factors influencing the reverse phase high performance liquid chromatography (RP-HPLC) determination of metaxalone in bulk and pharmaceutical dosage forms. The combined effect of buffer pH, % organic phase and flow rate, each at three levels was screened for responses such as retention time, tailing factor and number of theoretical plates. The responses were statistically optimized with the aid of response surface methodology using Box–Behnken experimental design (BBD). Phosphate buffer (pH 5): acetonitrile (41.74: 58.26 v/v) as eluent pumped at 0.8 ml/minflow rate was found to be the optimal condition to attain desired responses. The optimized method was further validated with respect to linearity, precision, accuracy and sensitivity according to the current regulatory requirements. Finally, the developed experimental design was validated by statistical analysis using one-way ANOVA showed that the proposed method was simple, sensitive, robust and represents an improvement over the existing methods for routine analysis of the metaxalone.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.002
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Methods · Consensus signal: Methods
Teacher disagreement score0.253
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0020.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.208
GPT teacher head0.465
Teacher spread0.257 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it