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Record W2097771278 · doi:10.1051/0004-6361/201014946

Submillimeter-wave spectrum of CH<sub>2</sub>D<sup>+</sup>

2010· article· en· W2097771278 on OpenAlexafffund
T. Amano

Bibliographic record

VenueAstronomy and Astrophysics · 2010
Typearticle
Languageen
FieldChemistry
TopicMolecular Spectroscopy and Structure
Canadian institutionsUniversity of Waterloo
FundersNatural Sciences and Engineering Research Council of CanadaUniversity of Waterloo
KeywordsPhysicsSpectral lineAtomic physicsHeliumIonAnalytical Chemistry (journal)Astronomy

Abstract

fetched live from OpenAlex

<i>Aims. <i/>Recently a tentative identification of CH<sub>2<sub/>D<sup>+<sup/> in interstellar space has been reported. To facilitate astronomical identifications, laboratory measurements of precise rest frequencies for the rotational lines of CH<sub>2<sub/>D<sup>+<sup/> should be carried out. <i>Methods. <i/>A submillimeter-wave spectrometer is used for detection of CH<sub>2<sub/>D<sup>+<sup/>. The CH<sub>2<sub/>D<sup>+<sup/> ion is generated in an extended negative glow discharge operated at liquid nitrogen temperature. The optimum gas mixture is found to be CH<sub>4<sub/> (~3 mTorr), CD<sub>4<sub/> (~1 mTorr), and H<sub>2<sub/> (~2 mTorr) in helium buffer. <i>Results. <i/>Four rotational lines have been detected in the frequency range of 280–890 GHz. The measured frequencies agree very well within a MHz with the predictions given by Rösslein et al. from the infrared spectra. <i>Conclusions. <i/>Two rotational lines of this ion have been tentatively identified toward Ori IRc2. The rest frequencies obtained here should facilitate identifications and analysis of astronomical spectra.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.059
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.004
GPT teacher head0.182
Teacher spread0.179 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations16
Published2010
Admission routes2
Has abstractyes

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