Volumetric Properties of Cyclic Alanylalanine in Aqueous Solutions of MnCl2, NiCl2 and ZnCl2 at Temperatures T = (293.15 to 313.15) K
Bibliographic record
Abstract
The partial molar volumes, isentropic compressibilities, partial molar isentropic compressions and transfer molar quantities of cyclic alanylalanine in water and in aqueous solutions of MnCl2, NiCl2 and ZnCl2 were determined using the experimental density and speed of sound values. Refractive indices of all the solutions were recorded to calculate the molar refractions. The molecular interactions existing in the systems have been discussed based on the derived parameters. It has been found that M2+-O2H bond distances of hydrated cations influence on the volumetric properties of cyclic alanylalanine. Further, the greater effect of hydrophobic hydration has been substantiated by the Sv values of least square fits of apparent molar volume against solute molality.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".