Poly(p-phenylenevinylene) derivatives: new promising materials for nonlinear all-optical waveguide switching
Bibliographic record
Abstract
Several new derivatives of poly(p-phenylenevinylene) (PPV) are investigated regarding their linear and nonlinear optical material and waveguide properties, including their nonlinear photonic bandgap properties that are induced by photoablated periodic Bragg gratings. The new materials were prepared by means of the polycondensation route, which yields polymers with excellent solubilities and film-forming properties. Comparative data suggest that the new polycondensation-type MEH-PPV (completely soluble, strictly linear and fully conjugated), in particular, is the most promising polymer under investigation to fulfill the requirements for all-optical switching in planar waveguide photonic bandgap structures. UV-photobleaching techniques and photoablation in the UV, VIS, and near-infrared ranges at different pulse durations are investigated. Homogeneous submicrometer gratings that serve as Bragg reflectors have been fabricated in MEH-PPV thin films by application of these methods. The great potential of this type of materials for nonlinear all-optical switching applications that arises from their unique optical properties and their patterning behavior is discussed in detail. Numerical simulations of a switching device based on gap-soliton formation in a nonlinear periodic waveguide structure with the newly obtained material data have been carried out. We show that one can expect photonic bandgap all-optical switching in MEH-PPV planar waveguides. Device performance considering different grating parameters is discussed.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.001 | 0.001 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.001 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".