First Photolysis of Benzidine Schiff Base in Non Aqueous Solvents
Bibliographic record
Abstract
The first photolysis of synthesized Schiff base [Bis-(2-chlorobenzalidene) benzidine] in the presence of varioussolvents (methanol, acetonitrile and n-hexane) was carried out under UV-light radiation. The data obtained byUV-Visible spectroscopy was used to determine the kinetic parameters of the Schiff base photolysis. It was foundthat the degradation of Schiff base in all solvents followed a first order reaction. The results show the rate ofphotolysis depends on the polarity of solvents. The effect of temperature on the photolysis process in methanol hasbeen studies at different temperature ranging from 10ºC to 50ºC. The activation energy has been determined. Theintermediates formed in the Schiff base photolysis processes were detected and identified, using High PerformanceLiquid Chromatography analytical technique coupled with UV-visible spectrophotometer.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.001 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.002 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".