MétaCan
Menu
Back to cohort
Record W2102204831 · doi:10.1039/c2dt00024e

Combining form with function – the dawn of phosphole-based functional materials

2012· article· en· W2102204831 on OpenAlexafffund
Yi Ren, Thomas Baumgartner

Bibliographic record

VenueDalton Transactions · 2012
Typearticle
Languageen
FieldChemistry
TopicSynthesis and characterization of novel inorganic/organometallic compounds
Canadian institutionsUniversity of Calgary
FundersNatural Sciences and Engineering Research Council of CanadaAlberta Innovates - Technology Futures
KeywordsPhospholeConjugated systemNanotechnologyMaterials scienceFunction (biology)Computer scienceChemistryOrganic chemistryPolymerBiology

Abstract

fetched live from OpenAlex

Phosphole-based π-conjugated compounds have recently attracted significant attention due their unique electronic properties. It is now well established that the versatile phosphorus chemistry offers great opportunities for efficient fine-tuning of the properties of π-conjugated systems from a fundamental point of view; a feature that pure carbon-based π-conjugated materials cannot provide. This perspective highlights the recent progress using phosphole-based π-conjugated building blocks towards applied materials with multiple and diverse functionalities.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.004
Threshold uncertainty score0.014

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.001
Scholarly communication0.0010.002
Open science0.0000.001
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0040.002

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.019
GPT teacher head0.205
Teacher spread0.186 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations216
Published2012
Admission routes2
Has abstractyes

Explore more

Same venueDalton TransactionsSame topicSynthesis and characterization of novel inorganic/organometallic compoundsFrench-language works237,207