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Record W2105011366 · doi:10.1002/cjce.22267

Solvent extraction of phenol from aqueous solution with benzyl 2‐ethylhexyl sulfoxide as a novel extractant

2015· article· en· W2105011366 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

venuePublished in a venue whose home country is Canada.
no affNo Canadian affiliation: this work is invisible to an affiliation-only frame.
No Canadian affiliation. An affiliation-only frame, the usual design, would never have seen this work. It is one of the works that make the case for inverting the frame.

Bibliographic record

VenueThe Canadian Journal of Chemical Engineering · 2015
Typearticle
Languageen
FieldEngineering
TopicExtraction and Separation Processes
Canadian institutionsnot available
FundersNational Key Research and Development Program of ChinaNatural Science Foundation of Yunnan ProvinceNational Natural Science Foundation of China
KeywordsPhenolChemistryAqueous solutionExtraction (chemistry)Aqueous two-phase systemSulfoxidePhenol extractionSolventSodium hydroxideInorganic chemistryOrganic chemistryNuclear chemistry

Abstract

fetched live from OpenAlex

In this paper, we synthesized a novel structure of sulfoxide, benzyl 2‐ethylhexyl sulfoxide (BSO), and evaluated its performance for extracting phenol. The influences of several variables on phenol extraction were investigated, including equilibrium time, pH value, temperature, and salts in the aqueous phase. It was found the BSO dissolved in kerosene was an effective extractant for the recovery of phenol from an aqueous solution at pH = 2. The transfer mechanism of phenol into the organic phase was proved to be the solvation reaction by BSO through hydrogen bonds as a phenol: BSO 1:1 complex. The temperature variation tests showed that the extraction process is exothermic, and phenol extraction efficiency decreased with increased reaction temperature. Phenol could be efficiently stripped from the loaded organic phase with a sodium hydroxide solution. The results obtained establish that the BSO/kerosene system has potential for practical applications in the recovery of phenol from aqueous solutions.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.118
Threshold uncertainty score0.457

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.018
GPT teacher head0.216
Teacher spread0.198 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it