Kinetics and Modeling of Solution ARGET ATRP of Styrene, Butyl Acrylate, and Methyl Methacrylate
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Bibliographic record
Abstract
Abstract This work reports a kinetic model for the activator‐regenerated‐by‐electron‐transfer atom‐transfer radical polymerization (ARGET ATRP) and its verification by the experimental data of solution ARGET ATRP of styrene, methyl methacrylate, and butyl arylate from literatures. The effects of ATRP equilibrium constant K and apparent reducing rate coefficient k r on the ARGET ATRP kinetics are investigated. A highly active initiation/catalyst system with a large K results in a poor control of the polymerization while an increased k r promotes the polymerization rate but the formation of dead polymer chains. Reducing agent with a moderate k r gives good control over ARGET ATRP. It is not feasible to use a moderate catalyst system for the ARGET ATRP of highly active monomers. magnified image
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it