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Record W2106003350 · doi:10.1002/app.13357

Study on nanometer‐size styrene‐butadiene multiblock copolymer synthesized by reactive extrusion

2003· article· en· W2106003350 on OpenAlexaff
Gao Shishuang, Ying Zhang, Huining Xiao

Bibliographic record

VenueJournal of Applied Polymer Science · 2003
Typearticle
Languageen
FieldChemistry
TopicAdvanced Polymer Synthesis and Characterization
Canadian institutionsUniversity of New Brunswick
Fundersnot available
KeywordsReactive extrusionCopolymerMaterials sciencePolymerizationStyrenePolymer chemistryStyrene-butadienePlastics extrusionPolymerExtrusionAnionic addition polymerizationFourier transform infrared spectroscopyChemical engineeringComposite material

Abstract

fetched live from OpenAlex

Abstract In this study, a novel styrene‐ b ‐butadiene block copolymer was synthesized by bulk anionic polymerization in a corotating closely intermeshing twin‐screw extruder. The structure of the S/B copolymer was determined by characterization methods including FTIR, NMR, dynamic mechanical analysis (DMA), and TEM. It is shown that the polymerized materials exhibit nanometer‐size styrene and butadiene (S/B) multiblock structure and ultrahigh elongation at break, which differs considerably from that of traditional solution polymerizing methods. In terms of the structure of the polymerized products, the mechanism of living anionic polymerization of S/B in a corotating intermeshing twin‐screw extruder is discussed. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 91: 2265–2270, 2004

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.017
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.011
GPT teacher head0.251
Teacher spread0.240 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations17
Published2003
Admission routes1
Has abstractyes

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