MétaCan
Menu
Back to cohort
Record W2106321593 · doi:10.1002/anie.200802966

Dinuclear Dysprosium(III) Single‐Molecule Magnets with a Large Anisotropic Barrier

2008· article· en· W2106321593 on OpenAlexaff
Po‐Heng Lin, T.J. Burchell, Rodolphe Clérac, Muralee Murugesu

Bibliographic record

VenueAngewandte Chemie International Edition · 2008
Typearticle
Languageen
FieldMaterials Science
TopicMagnetism in coordination complexes
Canadian institutionsUniversity of Ottawa
Fundersnot available
KeywordsDysprosiumSingle-molecule magnetLanthanideMagnetRelaxation (psychology)Quantum tunnellingMolecular magnetsMoleculeMagnetizationCrystallographyMaterials scienceChemistryPhysicsCondensed matter physicsQuantum mechanicsNuclear physicsPsychology

Abstract

fetched live from OpenAlex

Dysprosium-based single-molecule magnets: Single-molecule magnets (SMMs) of dinuclear dysprosium(III) having thermal and quantum tunneling regimes of magnetization relaxation have been synthesized. Remarkably large energy barriers up to 71 K are observed, in particular for the polymeric complex network, which has the largest energy gap for a lanthanide complex and one of the highest barriers reported for a SMM.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.002

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.016
GPT teacher head0.231
Teacher spread0.216 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations529
Published2008
Admission routes1
Has abstractyes

Explore more

Same venueAngewandte Chemie International EditionSame topicMagnetism in coordination complexesFrench-language works237,207