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Record W2109127100 · doi:10.1002/cjce.5450800109

A catalyst deposited over the external surface of the reactor tubes—A new solution for carrying out heterogeneous catalytic processes

2002· article· en· W2109127100 on OpenAlexvenueno aff
Asen I. Anastasov, Валентин Николов

Bibliographic record

VenueThe Canadian Journal of Chemical Engineering · 2002
Typearticle
Languageen
FieldChemical Engineering
TopicCatalysis and Oxidation Reactions
Canadian institutionsnot available
Fundersnot available
KeywordsPhthalic anhydrideCatalysisCoolantReagentChemical engineeringMaterials scienceSelectivityProcess (computing)Process engineeringChemistryEngineeringComputer scienceMechanical engineeringOrganic chemistry

Abstract

fetched live from OpenAlex

Abstract A mathematical model of a new reactor design has been proposed. In the new reactor the catalyst is deposited over the external surface of the tubes, where the coolant flows. The widespread industrial process of oxidation of o‐xylene into phthalic anhydride was investigated. The results obtained show significant advantages of the new design in comparison with the conventional fixed bed reactor operating in the industry. They are: much higher productivity, easily controlled temperature regime, raised selectivity and decrease content of side products, as well as an opportunity for additional feed‐in of the reagent along the reactor height. The technological regime of the oxidation process was optimized.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: none
Teacher disagreement score0.001
Threshold uncertainty score0.005

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.001
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0010.001
Bibliometrics0.0000.000
Science and technology studies0.0000.001
Scholarly communication0.0010.001
Open science0.0010.001
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0010.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.017
GPT teacher head0.206
Teacher spread0.190 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations3
Published2002
Admission routes1
Has abstractyes

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