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Record W2110190928 · doi:10.1002/elan.200390113

An Electrochemical Investigation of Complexation of Pb(II) by a Well‐Characterized Fulvic Acid in Model Systems – Effect of Competition with Major Cations and Trace Metals

2003· article· en· W2110190928 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueElectroanalysis · 2003
Typearticle
Languageen
FieldEnvironmental Science
TopicHeavy metals in environment
Canadian institutionsCarleton University
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsChemistryFulvic acidIonic strengthInorganic chemistryMetalTrace metalElectrochemistryAnodic stripping voltammetryTRACE (psycholinguistics)Stability constants of complexesIonic bondingStripping (fiber)IonHumic acidPhysical chemistryElectrodeMaterials scienceAqueous solution

Abstract

fetched live from OpenAlex

Abstract Effect of competition of major cations, Ca 2+ , Mg 2+ , and trace metals, Cu 2+ , Ni 2+ and Zn 2+ , on the stability of the Pb(II)‐fulvic acid (FA) complexes in model systems at constant pH and ionic strength was investigated by square‐wave anodic stripping voltammetry (SWASV). The results show that the trace metals compete with the target trace metal, Pb(II), for binding sites of the FA even when they are present in the same concentration as that of Pb(II), whereas the major cations compete with Pb(II) only when they are present in massive excess.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.053
Threshold uncertainty score0.565

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.005
GPT teacher head0.210
Teacher spread0.205 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it