Stability of Created Nano-Holes from Electrodeposited Organic SAMs (Thiols) on Gold Polycrystalline Films
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Bibliographic record
Abstract
Self-assembled monolayers CH 3 (CH 2 ) n-1 SH with different chain lengths have been elaborated by electrodeposition on gold films. Enhanced blocking properties were obtained by sweeping the potential between oxidative and reductive regions. Once complete and almost defects free layers were obtained, partial reduction was found to lead to the creation of almost circular nanosized holes in the SAMs; which can be used as nanoelectrodes. As verified by the EIS analysis of the charge and the mass transfer through the electrodeposited layers, the stability of the system permeability was found deeply depending on the chain length.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.002 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it