Crystal Growth and Structure of a New PbHNSO3 Crystal
Bibliographic record
Abstract
A new type of PbHNSO3 crystal has been grown by a gel method using agar-agar gel. TG-DTA and X-ray diffraction measurements have been performed on single crystal samples of PbHNSO3. It is found that the thermal decomposition of the compound starts at about 960 K. The space group (orthorhombic Pnma) and structural parameters are determined at room temperature with unit cell dimensions: a=8.4690(6), b=5.3934(4) and c=6.9530(4) Å. The crystal structure is found to consist of NSO3 pseudo-tetrahedra, PbO9N3 polyhedra, and NSO3-Pb-NSO3 frameworks. The dark brown color of the crystal is suggested to be caused by the absorption of blue wavelengths of light which is due to the excitation of excess electrons in potential wells produced by the NSO3-Pb-NSO3 framework.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.001 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".