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Record W2113726238 · doi:10.5194/amt-7-2337-2014

Tropospheric CH <sub>4</sub> signals as observed by NDACC FTIR at globally distributed sites and comparison to GAW surface in situ measurements

2014· article· en· W2113726238 on OpenAlexafffund
Elisa Sepúlveda, Matthias Schneider, Frank Hase, Sabine Barthlott, Darko Dubravica, Omaira García, Ángel J. Gómez-Peláez, Yenny González, Juan Carlos Guerra, M. Gisi, R. Kohlhepp, S. Dohe, Thomas Blumenstock, Kimberly Strong, Dan Weaver, Mathias Palm, Alireza Sadeghi, Nicholas M. Deutscher, Thorsten Warneke, Justus Notholt, Nicholas Jones, David Griffith, Dan Smale, Gordon Brailsford, John Robinson, Frank Meinhardt, Martin Steinbacher, Tuula Aalto, D. E. J. Worthy

Bibliographic record

VenueAtmospheric measurement techniques · 2014
Typearticle
Languageen
FieldEnvironmental Science
TopicAtmospheric and Environmental Gas Dynamics
Canadian institutionsEnvironment and Climate Change CanadaUniversity of Toronto
FundersNatural Sciences and Engineering Research Council of CanadaMinistry of Business, Innovation and EmploymentBundesamt für UmweltAntarctica New ZealandCanadian Foundation for Climate and Atmospheric SciencesAustralian Research CouncilNova Scotia Research Innovation TrustDepartment of Energy and Climate ChangeNational Aeronautics and Space AdministrationEurostarsCommonwealth Scientific and Industrial Research OrganisationU.S. Department of Energy
KeywordsTroposphereEnvironmental scienceRemote sensingIn situAtmospheric sciencesStratosphereFourier transformMeteorologyPhysicsGeography

Abstract

fetched live from OpenAlex

Abstract. We present lower/middle tropospheric column-averaged CH4 mole fraction time series measured by nine globally distributed ground-based FTIR (Fourier transform infrared) remote sensing experiments of the Network for the Detection of Atmospheric Composition Change (NDACC). We show that these data are well representative of the tropospheric regional-scale CH4 signal, largely independent of the local surface small-scale signals, and only weakly dependent on upper tropospheric/lower stratospheric (UTLS) CH4 variations. In order to achieve the weak dependency on the UTLS, we use an a posteriori correction method. We estimate a typical precision for daily mean values of about 0.5% and a systematic error of about 2.5%. The theoretical assessments are complemented by an extensive empirical study. For this purpose, we use surface in situ CH4 measurements made within the Global Atmosphere Watch (GAW) network and compare them to the remote sensing data. We briefly discuss different filter methods for removing the local small-scale signals from the surface in situ data sets in order to obtain the in situ regional-scale signals. We find good agreement between the filtered in situ and the remote sensing data. The agreement is consistent for a variety of timescales that are interesting for CH4 source/sink research: day-to-day, monthly, and inter-annual. The comparison study confirms our theoretical estimations and proves that the NDACC FTIR measurements can provide valuable data for investigating the cycle of CH4.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: Observational
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.011
Threshold uncertainty score0.022

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0010.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.024
GPT teacher head0.230
Teacher spread0.206 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations71
Published2014
Admission routes2
Has abstractyes

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