Designs for molecular circuits that use electronic coherence
Bibliographic record
Abstract
The mounting evidence of recent years regarding long-lived coherent dynamics of electronic excitations in several light-harvesting antenna proteins suggests the possibility of realizing and exploiting light-initiated quantum dynamics in synthetic molecular devices based on electronic energy transfer. Inspired by the field of molecular logic, we focus this discussion on the prospect of using quantum coherence to control the direction of energy flow in a molecular circuit. As a prototype system we consider a circuit consisting of three chromophores that deliver energy to two trap chromophores. Our aim is to control to which trap the energy is more likely to be delivered. This is achieved by switching one of the circuit chromophores ON and OFF from the system, such that the direction of energy flow substantially changes from the ON and OFF states of the circuit. We find that quantum coherence can allow a significant ability to direct energy transfer in the circuit. However, when realistic levels of noise are added, quantum coherence only slightly improves the ability to direct electronic energy in comparison to a classical hopping mechanism.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.001 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.001 |
| Scholarly communication | 0.001 | 0.001 |
| Open science | 0.001 | 0.001 |
| Research integrity | 0.001 | 0.001 |
| Insufficient payload (model declined to judge) | 0.005 | 0.001 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".